以雷射直寫技術於銀離子交換玻璃 製作表面增強拉曼基板

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姓名

林里旺(LIN,LI-WANG) 查詢紙本館藏

畢業系所

光電科學與工程學系

論文名稱

以雷射直寫技術於銀離子交換玻璃製作表面增強拉曼基板
(Fabrication of surface enhanced Raman substrate based on laser direct writing on Na+-Ag+ ion exchanged glass)

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摘要(中)

本論文利用以雷射直寫技術於銀離子交換玻璃製作表面增強拉曼基板，在以雷射寫出銀結構後以BOE (Buffered Oxide Etchant)進行蝕刻，並且對其進行石墨烯的轉移，量測其拉曼散射訊號，最後成功的量測到石墨烯的表面增強拉曼散射訊號，若能將基板進行表面平坦化後可作為一具有表面增強拉曼活性基板。

摘要(英)

This study describes the fabrication of a surface enhanced Raman substrate utilizing laser direct writing technology. After field-assisted ion exchanged process, a cw green laser light is used to reduce the in-diffused silver ions. Etching is subsequently performed using BDE (Buffered Oxide Etchant) to expose the nanostructures. Graphene is then transferred on top of the substrate, acting as a probe for the Raman-active substrate. Raman signatures such as the G-band and D-band are successfully measured which correlates closely with the measured surface profiles.

關鍵字(中)

★ 拉曼

關鍵字(英)

論文目次

中文摘要 iii
Abstract vi
誌謝 vii
目錄 viii
圖目錄 ix
表目錄 x
第一章緒論 1
1-1 前言 1
1-2研究動機 4
1-3論文架構 6
第二章研究方法 7
2-1銀離子熱還原之機制 7
2-2奧斯瓦爾德熟化 8
2-3銀離子光還原之機制 10
2-4拉曼光譜學簡介 11
2-5表面增強拉曼散射簡介 13
第三章實驗設計與架構 14
3-1樣品製作與實驗架構 14
3-1-1銀離子交換玻璃之製備 14
3-1-2利用雷射進行銀還原之方法 17
3-1-3石墨烯轉移至樣品上之方法 18
3-1-4拉曼散射量測架構 19
3-2原子力顯微鏡AFM((atomic force microscopy)簡介 20
3-2 SEM(scanning electron microscopy)簡介 21
第四章實驗結果與討論 22
第五章結論與展望 29
參考文獻 30

參考文獻

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指導教授

戴朝義(Tai, Chao-Yi)

審核日期

2024-1-30

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