中大學術數位典藏-NCU Institutional Repository:Item 987654321/105148
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    题名: Local anodic oxidation kinetics of chemical vapor deposition graphene supported on a thin oxide buffered silicon template
    作者: 溫偉源;Chuang, Min-Chiang;Chien, Hsiao-Mei;Chain, Yuan-Hong;Chi, Gou-Chung;Lee, Sheng-Wei;Woon, Wei Yen
    贡献者: 理學院物理學系
    关键词: Anodizing;atomic force microscopy;Buffers (chemistry);Chemical vapor deposition;copper;Cross-disciplinary physics: materials science;rheology;Exact sciences and technology;foil;Graphene;Materials science;Nanostructure;Other materials;Oxidation;Oxides;Physics;reaction kinetics;Silicon;Specific materials;spectroscopy;Strain;vapors
    日期: 2013-04-01
    上传时间: 2026-04-23 12:08:25 (UTC+8)
    出版者: Elsevier Ltd.;Kidlington: Elsevier Ltd
    摘要: 摘要: Study of local anodic oxidation (LAO) of single layer graphene (SLG) supported on thin oxide buffered silicon template is reported. Centimeter scaled SLG sheet grown through chemical vapor deposition on Cu foil is transferred onto patterned silicon template covered with thin oxide steps. LAO are performed on the supported SLG through contact mode atomic force microscopy in ambient condition. LAO bumps with heights exceed physical carbon–oxygen stacking are formed on thin oxide buffered samples. Micro-Raman spectroscopy reveals the coexistence of surface graphene oxide formation and local strain near the LAO patterns. The writing speed dependence of LAO bump shows a multi-exponent behavior, indicating inhomogeneous chemical profiles involved in the LAO process. The observation points to a sequential kinetics of surface SLG oxidation prior to subsurface silicon oxide protrusion formation. Our work shows the necessity to consider oxidation of substrate through the subsurface buffer layer during nano-scaled field effect device fabrication with LAO method. The strain generation from the subsurface protrusion suggests possible tuning knob for local distortion of SLG structure.
    出版者: Kidlington: Elsevier Ltd
    出版日期: 2013-04-01
    出處: Carbon, 2013-04, Vol.54, p.336-342
    資源來源: ScienceDirect
    版權: 2012 Elsevier Ltd
    版權: 2014 INIST-CNRS
    識別號: ISSN: 0008-6223
    識別號: EISSN: 1873-3891
    識別號: DOI: 10.1016/j.carbon.2012.11.045
    識別號: CODEN: CRBNAH
    显示于类别:[物理學系] 期刊論文

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