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    請使用永久網址來引用或連結此文件: https://ir.lib.ncu.edu.tw/handle/987654321/110115


    題名: 添加奈米纖維素於含鉍銦銲料之界面動力學研究;Interfacial Reaction Kinetics of Bismuth and Indium-Containing Solder with Cellulose Nanofibers Addition
    作者: 魏宇宏;HUNG, WEI YU
    貢獻者: 化學工程與材料工程學系
    關鍵詞: 電子封裝;銲料改質;奈米纖維素;Electronic Packaging;Solder Modification;Cellulose Nanofibers
    日期: 2026-09-01
    上傳時間: 2026-10-20 15:15:49 (UTC+8)
    出版者: 國立中央大學
    摘要: 中溫銲料目前已廣泛應用於半導體封裝,以及汽車與電力電子產品中。它們特別適用於多階段組裝製程中的階段式焊接(Step soldering),並可在製程過程中減少半導體複合基板產生的缺陷。本研究所使用的銲料為 Sn-Ag-Cu-Bi-In 合金。相較於廣泛使用的 SAC305 銲料,添加 In 可提供固溶強化效果,使 Sn-Ag-Cu-Bi-In 銲料在高溫服役條件下仍能維持良好的可靠度。然而,在高溫儲存過程中觀察到界面金屬間化合物層厚度顯著增加,此現象可能會降低接點的機械強度。因此,本研究將奈米纖維素(Cellulose Nanofibers, CNFs)摻入 Sn-Ag-Cu-Bi-In 焊膏中,以觀察銲料/Ni與焊料/Cu界面IMCs 的成長。根據實驗結果,添加 CNFs 能有效抑制界面 IMCs 在迴焊後(As-reflowed)與高溫儲存試片中的成長。上述結果顯示,CNFs 的摻入可能有助於提升銲點的可靠度與機械強度。;Medium-temperature solders are currently widely applied in semiconductor packaging, as well as in automotive and power electronic products. They are particularly suitable for step soldering in multi-stage assembly processes and for mitigating defects in semiconductor composite substrates during fabrication. In this study, the solder alloy employed was a Sn-Ag-Cu-Bi-In alloy. Compared with the widely used SAC305 solder, the addition of In provides solid-solution strengthening, enabling Sn-Ag-Cu-Bi-In solder to maintain good reliability under high-temperature service conditions. However, significant growth in the thickness of the interfacial intermetallic compounds (IMCs) layer was observed during high-temperature storage, which may deteriorate the mechanical strength of the joint. Therefore, cellulose nanofibers (CNFs) were doped into the Sn-Ag-Cu-Bi-In solder paste to suppress solder/Ni and solder/Cu interfacial IMCs growth. The experimental results show that the doping of CNFs effectively suppresses the growth of interfacial IMCs in both as-reflowed and high-temperature storage specimens. These findings suggest that CNFs doping may enhance the reliability and mechanical strength of the solder joint.
    顯示於類別:[化學工程與材料工程研究所] 博碩士論文

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