Steric effect and mobility of the alkyl chain in regio-irregular poly-3-alkylthiophenes

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/28369

Title:	Steric effect and mobility of the alkyl chain in regio-irregular poly-3-alkylthiophenes
Authors:	Wu,CG;Lin,YC;Chan,MJ;Chien,LN
Contributors:	中央大學
Keywords:	POLY(3-ALKYLTHIOPHENES);LENGTH;POLYTHIOPHENES;POLYMERIZATION;THERMOCHROMISM;DEPENDENCE;POLYMERS;BEHAVIOR;MODEL
Date:	1999
Issue Date:	2010-06-29 19:47:14 (UTC+8)
Publisher:	化學研究所
Abstract:	The physicochemical properties of polyalkylthiophenes with various sidechain length were widely investigated in order to reveal the functions of alkyl sidechains in these polymers. The effects of the side-chains on the properties of polyalkylthiophenes can be explained by their steric hindrance and mobility. The steric hindrance of alkyl chain affected not only the polymerization mechanism of the monomers but also the redox potential, interchain distance, charge transport properties, and film morphology. The mobility of the side-chain influences the rate of dedoping, heat of transitions of polymers. The structure regio-regularity, stability of polarons/bipolarons, film morphologies, and interchain interactions determine the optical and electric properties of polyalkylthiophenes. (C) 1999 John Wiley & Sons, Inc.
Relation:	JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
Appears in Collections:	[Graduate Institute of Chemistry] journal & Dissertation

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