Synthesis and structural characterization of the first organically templated vanadyl(IV) arsenato- and phosphato-oxalates: (C4H12N2)[VO(C2O4)HXO4] (X = As, P)

NCU Institutional Repository > 理學院 > 化學研究所 > 期刊論文 > Item 987654321/28370

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: http://ir.lib.ncu.edu.tw/handle/987654321/28370

题名:	Synthesis and structural characterization of the first organically templated vanadyl(IV) arsenato- and phosphato-oxalates: (C4H12N2)[VO(C2O4)HXO4] (X = As, P)
作者:	Tsai,YM;Wang,SL;Huang,CH;Lii,KH
贡献者:	中央大學
关键词:	MALEIC-ANHYDRIDE;IRON PHOSPHATES;CATALYSTS;OXIDATION;CRYSTAL
日期:	1999
上传时间:	2010-06-29 19:47:16 (UTC+8)
出版者:	化學研究所
摘要:	Two novel piperazinium vanadyl(IV) compounds, (C4H12N2) [VO(C2O4)HAsO4] (1) and (C4H12N2)[VO(C2O4)HPO4] (2), have been prepared under mild hydrothermal conditions and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and magnetic susceptibility. They adopt a one-dimensional structure in which ladder-like chains are constituted by the three-connected V and three-connected X (X = As for 1 and P for 2) centers. Within the infinite chains the oxalate group coordinates to each of the V centers as a bidentate ligand. They are the first inorganic/organic mixed-anion materials prepared in the vanadium arsenate and vanadium phosphate systems. Crystal data for 1: orthorhombic, P2(1)2(1)2(1), a = 6.5595(1) Angstrom, b = 12.4689(1) Angstrom, c = 14.6363(1) Angstrom, Z = 4. Crystal data for 2: as above, except a = 6.4022(4) Angstrom, b = 12.4735(8) Angstrom, c = 14.653(1) Angstrom. According to the results of TG analysis, both compounds are thermally stable to ca. 250 degrees C. Our magnetic study revealed that exchange coupling occurred between the nearest VO2+ centers along the infinite (-V-O-X-O)(2) chains. Good fits of the magnetic susceptibility data were obtained by using the Bonner and Fisher S = 1/2 linear chain model.
關聯:	INORGANIC CHEMISTRY
显示于类别:	[化學研究所] 期刊論文

文件中的档案:

档案	描述	大小	格式	浏览次数
index.html		0Kb	HTML	431	检视/开启

在NCUIR中所有的数据项都受到原著作权保护.

社群 sharing

数据加载中.....