Thermodynamic properties of novolac-type phenolic resin blended with poly(ethylene oxide)

NCU Institutional Repository > 理學院 > 化學研究所 > 期刊論文 > Item 987654321/28396

jsp.display-item.identifier=請使用永久網址來引用或連結此文件: http://ir.lib.ncu.edu.tw/handle/987654321/28396

题名:	Thermodynamic properties of novolac-type phenolic resin blended with poly(ethylene oxide)
作者:	Chu,PP;Wu,HD;Lee,CT
贡献者:	中央大學
关键词:	ASSOCIATION MODEL;PHASE-BEHAVIOR;POLYMER BLENDS;DEPENDENCE;ENTHALPY;ETHER
日期:	1998
上传时间:	2010-06-29 19:47:56 (UTC+8)
出版者:	化學研究所
摘要:	The thermodynamic properties of novolac type phenolic resin blended with poly(ethylene oxide) (PEO) were investigated by the Painter-Coleman association model (PCAM). Equilibrium constants and enthalpy corresponding to the interaction between phenolic and poly( ethylene oxide) were calculated from the Fourier transform infrared spectroscopy of low molecular weight analogues in dilute solutions. The association parameters of the model compounds are transferred to the corresponding polymers, to predict the Gibbs free energy, phase behavior, and the degree of hydrogen bonding in the polymer blend. The heat capacity (C-p) and the excess heat capacity (Delta C-p) are used to verify the validity of PCAM model on predicting the thermodynamics properties of phenolic/PEO blend. It is found that the hydrogen bonding interaction dominates at moderate temperatures, which is outweighed by the dispersion force at higher temperature or high PEO compositions. (C) 1998 John Wiley & Sons, Inc.
關聯:	JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS
显示于类别:	[化學研究所] 期刊論文

文件中的档案:

档案	描述	大小	格式	浏览次数
index.html		0Kb	HTML	504	检视/开启

在NCUIR中所有的数据项都受到原著作权保护.

社群 sharing