SOLVOLYSIS OF (E)-2-ARYL-2-CHLORO-5-FLUOROADAMANTANE AND (Z)-2-ARYL-2-CHLORO-5-FLUOROADAMANTANE - EVIDENCE FOR A COMPETITION BETWEEN SIGMA-PARTICIPATION AND PI-RESONANCE

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题名:	SOLVOLYSIS OF (E)-2-ARYL-2-CHLORO-5-FLUOROADAMANTANE AND (Z)-2-ARYL-2-CHLORO-5-FLUOROADAMANTANE - EVIDENCE FOR A COMPETITION BETWEEN SIGMA-PARTICIPATION AND PI-RESONANCE
作者:	LIU,KT;CHANG,LW;LEE,SM
贡献者:	中央大學
关键词:	CATIONS
日期:	1994
上传时间:	2010-06-29 19:49:03 (UTC+8)
出版者:	化學研究所
摘要:	Competition between sigma-participation by C-beta-C gamma and pi-resonance by alpha-aryl group could be illustrated from the decreasing of (Z)l(E) rate ratios with increasing electron releasing of aryl substituent in the solvolysis of titled substrates. Product studies gave rise to the question about the efficiency of the tool of borohydride trapping.
關聯:	TETRAHEDRON LETTERS
显示于类别:	[化學研究所] 期刊論文

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