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    請使用永久網址來引用或連結此文件: http://ir.lib.ncu.edu.tw/handle/987654321/39321


    題名: GRAFTED POLYMER LAYERS WITH CHAIN EXCHANGE - A MONTE-CARLO SIMULATION
    作者: LAI,PY
    貢獻者: 物理研究所
    關鍵詞: MOLECULAR-DYNAMICS;DENSITY PROFILE;INTERFACE;BRUSHES;MELTS
    日期: 1993
    上傳時間: 2010-07-08 14:12:01 (UTC+8)
    出版者: 中央大學
    摘要: By introducing a bead-group energy of adsorption with the grafting surface, we simulate the grafted polymer layer including chain exchange with the bulk solution using the bond-fluctuation model. The kinetics of adsorption is relatively rapid n short times and becomes much slower in later time as the layer is formed. rhe self-adjusted surface coverage is measured for different values of chain lengths and head-group energies. We also found that the polymer chains in a grafted layer are replaced by introducing shorter chains of identical head groups, which is also observed in recent experiments.
    關聯: JOURNAL OF CHEMICAL PHYSICS
    顯示於類別:[物理研究所] 期刊論文

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