電弱理論包含了玻色子偶合並且適當地描述光子與W玻色子間的偶合。新物理可能影響玻色子自身的交互作用和改變動量的分布(例如:增加cross section,與標準模型比較,光子的橫向動量(pT)增加)。因此,對於Wγ的測量可以提供一個好的機會去測試電弱理論的結構。這篇論文利用CMS探測器分析Wγ的cross section並選擇W衰變為電子當作訊號事件。這篇論文也利用數據分析去估算背景事件。最後,Wγ的測量cross section為12.5±2.0(系統誤差)pb。 The electroweak (EW) theory includes the tri-linear vector boson coupling and well describes the coupling of the photon to the W boson. New physics may affect the self-interactions of vector bosons and alter the kinematic distributions, for example, enhanced cross section and higher photon pT excess as compared to the Standard Model. Thus, the measurements of Wγ production provide a good opportunity to test the structure of the non-Abelian character of EW theory. This thesis presents a study for the cross-section measurement of Wγ production with electron and photon in final state at CMS at sqrt(s) = 10 TeV. A data-driven method of estimating background is also shown and the measured cross-section of Wγ production is 12.5 ± 2.0 (syst.) pb.