本實驗室開發的N-Heterocyclic carbene-pyridine-based ruthenium染料結構，成功運用在染料敏化太陽能電池，在2010年發表在Angew. Chem. Int. Ed.，表現出高效率(η = 9.69%)，超越過去公認所使用的N719染料(η = 8.98%)。 本論文則是以此結構為主體，合成出其含氟的多電子衍生物，預期其光電轉換效率有更進一步的突破。 The development of N-heterocyclic carbine-pyridine-based ruthenium dye structure in our laboratory, the successful use in dye-sensitized solar cells was published in Angew. Chem. Int. Ed.in 2010, showing high efficiency (η = 9.69%) beyond the recognized of N719 dye (η = 8.98%) in the past. Therefore, the main structure in this thesis is synthesized for the fluorine-containing derivative, which will expect to be good in the efficient performance.
