High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of an Open-Framework Uranyl Silicate with Nine-Ring Channels: Cs(2)UO(2)Si(10)O(22)

Please use this identifier to cite or link to this item: http://ir.lib.ncu.edu.tw/handle/987654321/50891

Title:	High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of an Open-Framework Uranyl Silicate with Nine-Ring Channels: Cs(2)UO(2)Si(10)O(22)
Authors:	Liu,HK;Chang,WJ;Lii,KH
Contributors:	化學學系
Keywords:	URANIUM SILICATE;CRYSTAL-STRUCTURES;GERMANATE;CORROSION;CHAINS;VAPOR;RB;CS
Date:	2011
Issue Date:	2012-03-27 18:12:16 (UTC+8)
Publisher:	國立中央大學
Abstract:	A new uranium(VI) silicate, Cs(2)UO(2)Si(10)O(22), has been synthesized by a high-temperature, high-pressure hydrothermal method and characterized by single-crystal X-ray diffraction, luminescence, and solid state NMR spectroscopy. It crystallizes in the monoclinic space group P2(1)/c (No. 14) with a = 12.2506(4) angstrom, b = 8.0518(3) angstrom, c = 23.3796(8) angstrom, beta = 90.011(2)degrees, and Z = 4. Its structure consists of silicate double layers in the ab plane which are connected by UO(6) tetragonal bipyramids via four equatorial oxygen atoms to form a 3D framework with nine-ring channels parallel to the b axis where the Cs(+) cations are located. The photoluminescence emission spectrum at room temperature consists of one broad structured band which is typical of uranyl. The (29)Si MAS NMR spectrum is consistent with the crystal structure as determined from X-ray diffraction, and the resonances in the spectrum are assigned. A comparison of related uranyl silicate structures is made.
Relation:	INORGANIC CHEMISTRY
Appears in Collections:	[Department of Chemistry] journal & Dissertation

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