有機環狀小分子目前應用於電洞傳輸材料或是太陽能電池甚少，加上先前文獻報導指出若分子能具有孔柱狀之排列堆積將有助於電荷的傳輸、保護鈣鈦礦晶體避免其降解等。我們以此為出發點，研究與設計兩系列環狀化合物。 第一系列為以Carbazole為donor，phenyl為π形成D-π-D-π環狀分子。第二系列為合成含有Imine bond之環狀化合物。分子合成尚在進行中。預期合成環狀分子後將其應用於元件中進行探討。;Organic macrocyclic molecules are rarely used in hole transporting materials or solar cells. According to literature reports, the arrangement and accumulation of molecule with pores and columns will help the transfer of charges, protect the perovskite crystals from degradation. Based on the above factors, we design 2 series macrocyclic molecules. First one use carbazole as donor and phenyl as π to build D-π-D-π heterocyclic compound. Other one is to synthesis of cyclic compounds containing imine bond. Molecular synthesis is still in progress. It is expected that after the synthesis of the cyclic molecule, it will be applied to the PSCs for discussion.
